Only one tonne of ethanol can be produced from 3.3 tonnes of wheat. Many co-products arise from the raw materials used in the process of producing ethanol, the major one being distiller’s dried grains with solubles (DDGS). Other products are carbondioxide and glycerine. In August, Adisseo, in cooperation with Ajinomoto Eurolysine, organised a mini-symposium on the subject in Strasbourg, France.
By Dick Ziggers
‘Variability and nutritional values of DDGS’ was the
subject of the presentation made by Cécile Gady, feedstuffs research manager at
Adisseo. From an earlier discussion it was already clear that feed millers need
a more precise definition of the nutritional content of the DDGS they are
buying. This will be a difficult task since the manufacturing process at the
ethanol plants is far from uniform. On the one side, DDGS quality depends on the
grain quality and/or starch quality that is used.On the other side, ethanol
fabrication adds variabilities such as pre-treatment effects, exogenous
additions of enzymes and yeasts (to ferment the starch), yeast quality, quality
of the recycled solubles, as well as drying temperature and time.
Gady begins her presentation with the
conclusion that bioethanol by-products are derived from complex processes
involving several sources of variation. “It then looks obvious to qualify DDGS
as variable byproducts,” she said. “But what are the nutritional specificities
of these by-products and what exactly do we mean by variation? Are we able to
deal with this variability?” Quite some questions to discuss. Research has shown
that considerable differences are observed among true amino acid digestibility
of corn DDGS samples. Also, the nutrient composition varied substantially among
DDGS with the greatest variation being found for the digestibility of lysine.
Also, the metabolisable energy content of corn DDGS in poultry is more
controversial. Recent estimates of energy are substantially higher than values
reported in the NRC (1994, AME 2480 kcal/kg). Studies in broilers and turkeys
show differences varying from 350 to 425 kcal/kg higher values.
content and true
amino acid digestibility in poultry. Here it can also be concluded that there is
a high variability. Data on the metabolisable energy content of wheat DDGS is
more controversial. Recent estimates of energy are substantially higher than the
value reported by French research institute INRA (2004). Values vary from as low
as 1,820 kcal/kg (INRA, broilers) to as high as 2,676 kcal/kg (Arvalis,
roosters). However, Gady said that measurements are mainly affected by the
methodology applied, as well as the use of unclear and out-of-date product
segmentation.
In conclusion, it becomes clear that for
wheat and corn DDGS there is large variability in crude fibre, fat, ash, lysine
and tryptophan, and also low lysine and cystine digestibilities with high
variability. For wheat DDGS there is a lack of work on energy digestibility, and
for corn DDGS there is lack of consensus on energy digestibility. “A possible
explanation for this is the addition of recycled solubles in different
proportions,” said Gady.
Differences in processing
technologies and conditions, such as possible heat damage, also contribute to
variation. Furthermore, there could be interactions with enzymes and yeasts that
are added during the process. Composing a feed recipe is therefore difficult.
“Nutritionists need consistency and predictability in the feed ingredients,” she
said.
NIRS maybe a solution
A promising technology that could
predict variability fast and accurately is NIRS. Here, a coherent database needs
to be established that is useable for corn and wheat DDGS. Laboratory data and
NIRS data perfectly match in a linear way, with a balanced distribution of
outcomes. Adisseo research showed good NIRS calibrations of total amino acids
(R2>95%) and of amino acid digestibility (R2>80%), except for digestible
tryptophan (R2=66%). Prediction errors associated to the models vary from 2 to
6%, except for digestible lysine (E=9%). Gady’s general conclusion is that
although the ethanol process will further evolve, this evolution will have a
direct impact on the quality of DDGS both now and in the future. The industry
will continue to generate variable by-products, even if efforts are
made for
standardising production.
Consequences for the market
The shift in market demand for cereals
for fuel instead of feed has implications for feed formulators. Figures for 2006
show that cereal utilisation exceeded production. This shortage was then
balanced using the
cereals in stock, which resulted
in a world stock that decreased rapidly. For 2007, utilisation and production
are in balance, but stock cannot be replenished, except on a regional level. On
the other hand, the world market for protein-rich feedstuffs is in a continuous
increase and will reach 250 million tonnes in 2007/08. According to trading
specialist AC Toepfer Int., soybean meal is the main source of vegetable
proteins followed by rape/canola, and then corn gluten feed/DDGS. There will be
a shift in protein sources in Europe in the coming years. Total oil meal and
expellers is expected to increase from 45.2 million tonnes in 2004/05 to 48.8
million tonnes in 2010. Within this group of raw materials there will be less
soybean meal, more rape seed meal, less sunflower and a significant rise in DDGS
availability (Table 3
).
This shift, together with the developments in the biofuel sector, will have
economic consequences. Piet van der Aar, managing director of Schothorst Feed
Research in the Netherlands, summarised the effects of the biofuel industry on
feed formulation. “Biofuels set the price,” he said. “Cereals will be prised at
a higher level and starch sources will become scarcer. The availability of
protein sources will change and higher feed costs are expected. The energy value
of raw materials will become more important and variation in quality should be
known,” said Van der Aar. He also pointed at the increased availability of
rapeseed meal and expellers from the biodiesel industry. Furthermore, glycerol
is a new ingredient which the feed industry is unfamiliar with dealing with.
Price competition
As we can already see today, there is a
strong price competition in raw materials in concurrence with price fluctuations
of crude mineral oil. A higher oil price implies a higher price to be paid for
cereals to be used for biofuel production. For example, if the oil price is $60
(per barrel) the biofuel industry can pay $4.30 – $4.60 per bushel of maize
($175/t) to make a $0.33 litre of vegetable fuel. If the oil price rises to $70,
a bushel of maize can be purchased for $5.40 – $5.70 ($220/t) and vegetable fuel
price increases to $0.36 per litre. It goes without saying that this is tough
competition for the feed industry.
Nutritional effects
Because the fuel industry extracts a
lot of starch from the market, protein will become relatively cheaper. This will
result in higher protein concentrations in diets and will also increase the
risks of more gastro-intestinal disorders in animals. More protein also has a
negative effect on nitrogen and ammonia emissions.
“We are taking the starch
away from the feed, but what is the effect of this on the animal?” asks Van der
Aar. The level of starch in the diet has
an effect on stimulation of protein
deposition – the protein-fat ratio in the diet. Also, fertility is affected and
yolk-albumen ration in eggs might change
if starch levels decrease.
Additionally, feed and food safety will be challenged with the increased use of
DDGS, explained Van der Aar. A concentration of contaminants can occur,
specifically mycotoxins. Pigs are very susceptible to these toxins. Residues of
crop protection agents can also enter the feed chain through DDGS. Furthermore,
the US will try to export their surplus of DDGS; however, antibiotics used as
production aids in the US might hamper exports to Europe. The EU has a
zerotolerance for in-feed antibiotics. Another co-product of ethanol production
is glycerol. Although trials have shown that it can be used as a feed
ingredient, glycerol in feed is prohibited in the US due to possible methanol
residues from the production process. The use of these new ingredients can
affect husbandry aspects, and can also alter the quality of animal products.
Here, one can think of saturation of fat, water holding capacity, litter quality
and indirect effects on animal health.
Inclusion levels
In terms of costs, DDGS has different values depending on
the feeds it is
used in. Table 4 shows
the value of wheat DDGS in different feeds. Nutritionally, research for maximum
levels of critical compounds (glucosinolates, unsaturated fatty acid, soluble
NSPs) is required. The levels of inclusion depend on levels of critical
compounds in other ingredients used. What will the input for least-cost
formulations be? There are more restrictions for the use of biofuel products.
The use of rape products is limited due to their ANF content (glucosinates,
saponins). There is little knowledge about the net energy value of glycerol, and
DDGS varies too much in terms of quality, protein digestibility and fermentable
NSPs. What about the high P and N excretion? Taken all these factors into
account, Van der Aar generated possible practical incorporation levels for
wheat DDGS. These are illustrated
in Table 5. The availability of protein-rich ingredients and the
greater demand for starch for biofuels means that the feed industry is faced
with more expensive starch sources. This also results in less starch in the
diet. There will also be more pressure on glucose precursors in the diet.
Minimum starch requirements need to be re-evaluated regarding physiological
requirements, optimal production and energy requirements.
Source: Feed Tech magazine, Issue
11.8